Ncert Solution Class 12th Physics Chapter – 13 Nuclei
Textbook | NCERT |
class | Class – 12th |
Subject | Physics |
Chapter | Chapter – 13 |
Chapter Name | Nuclei |
Category | Class 12th Physics Question & Answer |
Medium | English |
Source | last doubt |
Ncert Solution Class 12th Physics Chapter – 13 Nuclei
?Chapter – 13?
✍Nuclei✍
?Question & Answer?
Q .1 (a) Two stable isotopes of lithium 6Li3 and7Li3 have respective abundances of 7.5% and 92.5%. These isotopes have masses 6.01512 u and 7.01600 u, respectively. Find the atomic mass of lithium.
(b) Boron has two stable isotopes, 10B5 and 11B5 . Their respective masses are 10.01294 u and 11.00931 u, and the atomic mass of boron is 10.811 u. Find the abundances of 10B5 and 11B5.
Answer:
(a) Mass of 6Li3, lithium isotope, m 1 = 6.01512 u
Mass of 7Li3, lithium isotope, m = 7.01600 u
Abundance of 6Li3 , η1 = 7.5%
Abundance of 7Li3 , η2 = 92.5%
The atomic mass of lithium atom is given as:
( b ) Mass of boron isotope 10B5 , m = 10.01294 u
Mass of boron isotope 11B5 , m = 11.00931 u
Abundance of 10B5, η1 = x %
Abundance of 11B5, η2 = (100 − x ) %
Atomic mass of boron, m = 10.811 u The atomic mass of boron atom is given as:
And 100 − x = 80.11%
Hence, the abundance of is 10B5 19.89% and that of 11B5 is 80.11%.
Q .2 The three stable isotopes of neon: 20Ne10, 21Ne10 and 22Ne10 have respective abundances of 90.51%, 0.27% and 9.22%. The atomic masses of the three isotopes are 19.99 u, 20.99 u and 21.99 u, respectively. Obtain the average atomic mass of neon.
Answer:
Atomic mass of 20Ne10, m1 = 19.99 u
Abundance of 20Ne10, η1 = 90.51%
Atomic mass of 21Ne10, m2 = 20.99 u
Abundance of 21Ne10, η2 = 0.27%
Atomic mass of 22Ne10, m3 = 21.99 u
Abundance of 22Ne10, η3 = 9.22%
The average atomic mass of neon is given as:
Q .3 Obtain the binding energy (in MeV) of a nitrogen nucleus (14/7 N) , given m(14/7 N) =14.00307 u
Answer:
Atomic mass of nitrogen
(7N14)
, m = 14.00307 u
A nucleus of nitrogen
7N14
contains 7 protons and 7 neutrons.
Hence, the mass defect of this nucleus, Δm = 7mH + 7mn − m
Where,
Mass of a proton, mH = 1.007825 u
Mass of a neutron, mn= 1.008665 u
∴Δm = 7 × 1.007825 + 7 × 1.008665 − 14.00307
= 7.054775 + 7.06055 − 14.00307
= 0.11236 u
But 1 u = 931.5 MeV/c2
∴Δm = 0.11236 × 931.5 MeV/c2
Hence, the binding energy of the nucleus is given as:
Eb = Δmc2
Where,
c = Speed of light
∴Eb = 0.11236 × 931.5
(MeV/c2)×c2
= 104.66334 MeV
Hence, the binding energy of a nitrogen nucleus is 104.66334 MeV.
Q .4 Obtain the binding energy of the nuclei 56/26 Fe and 209/83 Bi in units of MeV from the following data: m(56/26 Fe) = 55.934939 u m(209/83 Bi) = 208.980388 u
Answer:
Atomic mass of
56/26 Fe
, m1 = 55.934939 u
56/26 Fe
nucleus has 26 protons and (56 − 26) = 30 neutrons
Hence, the mass defect of the nucleus, Δm = 26 × mH + 30 × mn − m1
Where,
Mass of a proton, mH = 1.007825 u
Mass of a neutron, mn = 1.008665 u
∴Δm = 26 × 1.007825 + 30 × 1.008665 − 55.934939
= 26.20345 + 30.25995 − 55.934939
= 0.528461 u
But 1 u = 931.5 MeV/c2
∴Δm = 0.528461 × 931.5 MeV/c2
The binding energy of this nucleus is given as:
Eb1 = Δmc2
Where,
c = Speed of light
∴Eb1 = 0.528461 × 931.5
MeV/c2×c2
= 492.26 MeV
Average binding energy per nucleon
Atomic mass of
209/83 Bi
, m2 = 208.980388 u
209/83 Bi
nucleus has 83 protons and (209 − 83) 126 neutrons.
Hence, the mass defect of this nucleus is given as:
Δm‘ = 83 × mH + 126 × mn − m2
Where,
Mass of a proton, mH = 1.007825 u
Mass of a neutron, mn = 1.008665 u
∴Δm‘ = 83 × 1.007825 + 126 × 1.008665 − 208.980388
= 83.649475 + 127.091790 − 208.980388
= 1.760877 u
But 1 u = 931.5 MeV/c2
∴Δm‘ = 1.760877 × 931.5 MeV/c2
Hence, the binding energy of this nucleus is given as:
Eb2 = Δm‘c2
= 1.760877 × 931.5
MeV/c2×c2
= 1640.26 MeV
Average bindingenergy per nucleon =
Q .5 A given coin has a mass of 3.0 g. Calculate the nuclear energy thatwould be required to separate all the neutrons and protons fromeach other. For simplicity assume that the coin is entirely made of6329Cu atoms (of mass 62.92960 u).
Answer:
Given: The mass of a copper coin 3 g, the atomic mass of copper 29 63 Cu is 62.92960 u
The total numbers of atoms in the coin are given as,
N= N A ×m A
Where, Avogadro number is N A , the number of atoms are N, the mass number of copper A and the mass of a copper coin is m.
By substituting the given values in the above equation, we get
N= 6.022× 10 23 ×3 63 =2.868× 10 22 atoms
The number of protons in the nucleus of 29 63 Cuis 29 and the number of neutrons in the nucleus of 29 63 Cuis 34.
The mass defect of the nucleus of copper atom is given as,
Δ m ′ =29 m p +34 m n −m
Where, the mass of proton is m p , the mass of neutron is m n and the mass defect of the nucleus is Δ m ′ .
By substituting the given values in the above equation, we get
Δ m ′ =29×1.007825+34×1.008665−62.9296 =29.226925+34.29461−62.9296 =0.591935 u
The mass defect of all the atoms present in the coin is given as,
Δm=Δ m ′ ( N )
By substituting the given values in the above equation, we get
Δm=0.591935×2.868× 10 22 =1.69766958× 10 22 u
The binding energy of the nucleus of iron is given as,
E=Δm c 2
Where, the speed of light is c and the binding energy is E.
By substituting the given values in the above equation, we get
E=1.69766958× 10 22 c 2 ×931.5 MeV/ c 2 =1.584× 10 25 ×1.6× 10 −13 J =2.535× 10 12 J
Thus, the amount of energy required to separate all the neutrons and protons from the given coin is 2.535× 10 12 J.
Q .6 Write nuclear reaction equations for
(i) α-decay of 22688 Ra
(ii) α-decay of 24294 Pu
(iii) β–-decay of 3215 P
(iv) β–-decay of 21083 Bi
(v) β+-decay of 116 C
(vi) β+-decay of 9743 Tc
(vii) Electron capture of 12054 Xe
Answer:
• In alpha decay the mass number is reduced by four and the atomic number by two R 86 224 a.
• P 92 238 u
• In beta minus decay the P 15 32 → S 16 32 + β −1 0
• B 83 210 i→ P 84 210 o+ β −1 0
• After beta plus decay C 6 11 → B 5 11 + β 1 0 +
• After beta plus decay T 43 97 c→ M 42 97 o
• When the electron is captured by the xenon then
• X 54 12 e+ e −1 → I 53 120
Q .7 A radioactive isotope has a half-life of T years. How long will it takethe activity to reduce to a) 3.125%, b) 1% of its original value?
Answer:
a) Given: The half life of the radioactive isotope is T years and the reduction in the activity is 3.125%.
According to the law of radioactive decay,
N= N 0 e −λt N N 0 = e −λt
Where, N is the remaining number of molecules, N 0 is the initial number of atoms, λ is the decay constant and t is the time.
By substituting the given values in the above expression, we get
3.125 100 = e −λt 1 32 = e −λt λt= log e ( 32 ) t= 3.4657 λ
We know that,
λ= 0.693 T
By substituting the given value in the above expression, we get
t= 3.466 0.693 T =5T years
Thus, the isotope will take about 5T years to reduce to 3.125% of its original value.
b) Given: The reduction in the activity is 1%.
According to the law of radioactive decay,
N= N 0 e −λt N N 0 = e −λt
By substituting the given values in the above expression, we get
1 100 = e −λt 1 100 = e −λt λt= log e ( 100 ) t= 4.6052 λ
We know that,
λ= 0.693 T
By substituting the given value in the above expression, we get
t= 4.0652 0.693 T =6.65T years
Thus, the isotope will take about 6.65T years to reduce to 1% of its original value.
Q 13.8: The normal activity of living carbon-containing matter is found to be about 15 decays per minute for every gram of carbon. This activity arises from the small proportion of radioactive 14/6C present with the stable carbon isotope 12/6C . When the organism is dead, its interaction with the atmosphere (which maintains the above equilibrium activity) ceases and its activity begins to drop. From the known half-life (5730 years) of 14/6C , and the measured activity, the age of the specimen can be approximately estimated. This is the principle of 14/6C dating used in archaeology. Suppose a specimen from Mohenjodaro gives an activity of 9 decays per minute per gram of carbon. Estimate the approximate age of the Indus-Valley civilisation.
Answer:
Decay rate of living carbon-containing matter, R = 15 decay/min
Let N be the number of radioactive atoms present in a normal carbon- containing matter.
Half life of
14/6C
T 1/2
= 5730 years
The decay rate of the specimen obtained from the Mohenjodaro site:
R‘ = 9 decays/min
Let N’ be the number of radioactive atoms present in the specimen during the Mohenjodaro period.
Therefore, we can relate the decay constant, λand time, t as:
Hence, the approximate age of the Indus-Valley civilisation is 4223.5 years.
Q .9 Obtain the amount of 60/27 C0 necessary to provide a radioactive source of 8.0 mCi strength. The half-life of 60/27 C0 is 5.3 years.
Answer:
The strength of the radioactive source is given as:
Where,
N = Required number of atoms
Half-life of
60/27 C0
T 1/2
= 5.3 years
= 5.3 × 365 × 24 × 60 × 60
= 1.67 × 108 s
For decay constant λ, we have the rate of decay as:
dN/dt = λ N
Where, λ
For
27C060
Mass of 6.023 × 1023 (Avogadro’s number) atoms = 60 g
∴Mass of
7.133×1016
atoms
Hence, the amount of
27C060
necessary for the purpose is 7.106 × 10−6 g.
Q .10 The half-life of 90/38 Sr is 28 years. What is the disintegration rate of 15 mg of this isotope?
Answer:
Half life of
90/38 Sr
t 1/2
= 28 years
= 28 × 365 × 24 × 60 × 60
= 8.83 × 108 s
Mass of the isotope, m = 15 mg
90 g of
90/38 Sr
atom contains 6.023 × 1023 (Avogadro’s number) atoms.
Therefore, 15 mg of
90/38 Sr
contains:
Rate of disintegration,
dN/dt = λ N
Where,
λ = Decay constant
Hence, the disintegration rate of 15 mg of the given isotope is
7.878 × 1010 atoms/s.
Q 11. Obtain approximately the ratio of the nuclear radii of the gold isotope 19779 Au and the silver isotope 10747 Ag ..
Answer:
The mass number of gold isotope A 79 197 uis 197 and the mass number of silver isotope A 47 107 g is 107.
The radius of an isotope is directly proportional to its mass number.
R∝ A 1 3
Where, R is the radius of the nucleus and A is the mass number.
The ratio of radii of two nuclei is given as,
R Au R Ag = ( A Au A Ag ) 1 3
By substituting the given values in above equation, we get
R Au R Ag = ( 197 107 ) 1 3 =1.2256 ≈1.23
Thus, the ratio of nuclear radii of gold and silver isotopes is 1.23.
Q .12 Find the Q-value and the kinetic energy of the emitted α-particle in the α-decay of (a) 226/88 Ra and (b) 220/86 Rn Given m(226/88 Ra) = 226.02540 u, m(222/86 Rn) = 222.01750 u,m(220/86 Rn)= 220.01137 u, m(216/84 Po) = 216.00189 u.
Answer: Alpha particle decay of 226/88Ra emits a helium nucleus. As a result, its mass number reduces to (226 − 4) 222 and its atomic number reduces to (88 − 2) 86. This is shown in the following nuclear reaction.
Q-value of
emitted α-particle = (Sum of initial mass − Sum of final mass) c2
Where,
c = Speed of light
It is given that:
Q-value = [226.02540 − (222.01750 + 4.002603)] u c2
= 0.005297 u c2
But 1 u = 931.5 MeV/c2
∴ Q = 0.005297 × 931.5 ≈ 4.94 MeV
Kinetic energy of the α-particle =
= 222/226×4.94 = 4.85 MeV
Q .13 The radionuclide 11C decays according to
The maximum energy of the emitted positron is 0.960 MeV.
Given the mass values:
calculate Q and compare it with the maximum energy of the positron emitted
Answer:
The given nuclear reaction is:
Atomic mass of
m(11/6 )C
= 11.011434 u
Atomic mass of
m(11/6 B) = 11.009305
Maximum energy possessed by the emitted positron = 0.960 MeV
The change in the Q-value (ΔQ) of the nuclear masses of the
(11/6 )C
nucleus is given as:
Where,
me = Mass of an electron or positron = 0.000548 u
c = Speed of light
m’ = Respective nuclear masses
If atomic masses are used instead of nuclear masses, then we have to add 6 me in the case of
11C
and 5 me in the case of11B
Hence, equation (1) reduces to:
∴ΔQ = [11.011434 − 11.009305 − 2 × 0.000548] c2
= (0.001033 c2) u
But 1 u = 931.5 Mev/c2
∴ΔQ = 0.001033 × 931.5 ≈ 0.962 MeV
The value of Q is almost comparable to the maximum energy of the emitted positron.
Q .14 The nucleus 2310 Ne decays by β–emission. Write down the β-decay equation and determine the maximum kinetic energy of theelectrons emitted. Given that:m (2310 Ne ) = 22.994466 um (2311 Na ) = 22.089770 u.
Answer:
Given: The mass of N 10 23 e is 22.994466 u and the mass of N 11 23 ais 22.989770 u.
In β − emissions, the numbers of protons are increased by one and one antineutrino and one electron emitted from the parent nucleus.
The reaction of β − emission is given as,
N 10 23 e → N 11 23 a+ e − + v ¯ +Q
The Q-value for the reaction is given as,
Q-value=( m i − m f ) c 2 =[ m( N 10 23 e )−m( N 11 23 a ) ] c 2 (1)
Where, the sum of initial mass is m i and the sum of final mass is m f .
By substituting the given values in equation (1), we get
Q-value=[ 22.994466−22.089770 ]u ( c ) 2 =[ 0.004696 c 2 ]u (2)
We know that,
1 u=931.5 MeV/ c 2 (3)
By substituting the values of equation (3) in equation (2), we get
Q-value=0.004696×931.5 =4.374 MeV
The daughter nuclei is too heavy that it has negligible kinetic energy. The kinetic energy of antineutrino is almost zero.
The total kinetic energy is equal to the Q-value.
K.E.=4.374 MeV
Thus, the kinetic energy of emitted electrons is 4.374 MeV.
Q .15 The Q value of a nuclear reaction A+b⟶C+d is defined by Q = [ mA+ mb− mC− md]c2 where the masses refer to the respective nuclei. Determine from the given data the Q-value of the following reactions and state whether the reactions are exothermic or endothermic.
Atomic masses are given to be
Answer:
The given nuclear reaction is:
It is given that:
Atomic mass m(1/1H) = 1.007825 u
Atomic mass m(1/3H) = 3.016049 u
Atomic mass m(1/2H)=2.014102u
According to the question, the Q-value of the reaction can be written as:
Q = (- 0.00433 c2)u
But 1 u = 931.5 MeV/c2
=[1.007825 +3.016049-2×2.014102]c2
Q =-0.00433×931.5=-4.0334 MeV
The negative Q-value of the reaction shows that the reaction is endothermic.
Q .16 Suppose, we think of fission of a 5626Fe nucleus into two equalfragments, 2813 Al . Is the fission energetically possible? Argue byworking out Q of the process. Given m ( 5626Fe ) = 55.93494 u andm ( 2813 Al ) = 27.98191 u.
Answer:
Given: The mass of F 26 56 e is 55.93494 u and the mass of A 13 28 l is 27.98191 u.
The fission of F 26 56 e is given by,
F 26 56 e → 2 A 13 28 l
The Q-value of this reaction is given as,
Q-value=( m i − m f ) c 2 =[ m( F 26 56 e )−2×m( A 13 28 l ) ] c 2
Where, the sum of initial mass is m i and the sum of final mass is m f .
By substituting the given values in the above equation, we get
Q-value=[ 55.93494−2×27.98191 ] c 2 u =[ 55.93494−55.96382 ] c 2 u =−0.02888 c 2 u
We know that,
1 u=931.5 MeV/ c 2
Therefore, the Q-value is,
Q-value=−0.02888 c 2 ×931.5 MeV/ c 2 =−26.902 MeV
The Q-value for the fission reaction is negative. For an energetically possible fission reaction, the Q-value must be positive.
Thus, the fission is not possible.
Q .17 The fission properties of 23994 Pu are very similar to those of 23592 U . Theaverage energy released per fission is 180 MeV. How much energy,in MeV, is released if all the atoms in 1 kg of pure 23994 Pu undergofission?
Answer:
Given: The average energy released per fission of P 94 239 u is 180 MeV and the amount of P 94 239 u is 1 kg.
239 gof P 94 239 u contains 6.023× 10 23 atoms.
Let N be the number of atoms present in 1 kgof P 94 239 u.
The number of atoms contain by 1 kg of P 94 239 u is given by,
N= 6.023× 10 23 239 ×1000 =2.52× 10 24 atoms
Let E t be the total energy released in the fission.
E t =E×N
Where, the average energy released per fission of P 94 239 uis E.
By substituting the given values in above equation, we get.
E t =180×2.52× 10 24 =4.536× 10 26 MeV
Thus, the energy released by the fission of 1 kgof P 94 239 uis 4.536× 10 26 MeV.
Q .18 A 1000 MW fission reactor consumes half of its fuel in 5.00 y. How much 235/92 U did it contain initially? Assume that the reactor operates 80% of the time, that all the energy generated arises from the fission of 235/92 U and that this nuclide is consumed only by the fission process.
Answer:
Half life of the fuel of the fission reactor,
t1/2 = 5
years
= 5 × 365 × 24 × 60 × 60 s
We know that in the fission of 1 g of
235/92 U
nucleus, the energy released is equal to 200 MeV.
1 mole, i.e., 235 g of
235/92 U
contains 6.023 × 1023 atoms.
∴1 g
235/92 U
contains
6.023×1023/235 atoms.
The total energy generated per gram of
235/92 U
is calculated as:
The reactor operates only 80% of the time.
Hence, the amount of
235/92 U
consumed in 5 years by the 1000 MW fission reactor is calculated as:
∴Initial amount of
235/92 U
= 2 × 1538 = 3076 kg
Q .19 How long can an electric lamp of 100W be kept glowing by fusion of 2Kg of deuterium? Take fusion reaction is 1H2 + 1H2 = 2He4 + n+ 3.27MeV
Answer:
The given fusion reaction is:
Amount of deuterium, m = 2 kg
1 mole, i.e., 2 g of deuterium contains 6.023 x 1023 atoms.
And 2.0 kg of deuterium contains
It can be inferred from the given reaction that when two atoms of deuterium fuse, 3.27 MeV energy is released.
Total energy per nucleus released in the fusion reaction:
Power of the electric lamp, P = 100 W = 100 J/s
Hence, the energy consumed by the lamp per second = 100 J
The total time for which the electric lamp will glow is calculated as:
Q .20 Calculate the height of the potential barrier for a head on collisionof two deuterons. (Hint: The height of the potential barrier is givenby the Coulomb repulsion between the two deuterons when theyjust touch each other. Assume that they can be taken as hardspheres of radius 2.0 fm.)
Answer:
Given, the radius of deuteron nucleus is 2 fm.
Let the distance between the centres of two deuterons be d.
Formula for the distance dbetween the two deuterons is, d=radius of 1 deuteron +radius of 2 deuteron
Substitute the values in the above equation.
d=2× 10 −15 +2× 10 −15 =4× 10 −15 m
Charge on a deuteron nucleus is e=1.6× 10 −19 C
Potential energy of the two-deuteron system is given by,
V= e 2 4π ε ° d
Here, ε 0 is the permittivity of free space..
Substituting the values in the above equation, we get:
V= e 2 4π ε ° d = ( 1.6× 10 −19 ) 2 4×π×8.85× 10 −12 ×4× 10 −15 =360 keV
Thus, the height of the potential barrier of the two-deuteron system is 360 keV.
Q .21 From the relation R = R0A1/3, where R0 is a constant and A is the mass number of a nucleus, show that the nuclear matter density is nearly constant (i.e. independent of A).
Answer:
We have the expression for nuclear radius as:
R = R0A1/3
Where,
R0 = Constant.
A = Mass number of the nucleus
Nuclear matter density,
Let m be the average mass of the nucleus.
Hence, mass of the nucleus = mA
Hence, the nuclear matter density is independent of A. It is nearly constant.
Q .22 For the β+ (positron) emission from a nucleus, there is another competing process known as electron capture (electron from an inner orbit, say, the K−shell, is captured by the nucleus and a neutrino is emitted).
Show that if β+ emission is energetically allowed, electron capture is necessarily allowed but not vice−versa.
Answer: Let the amount of energy released during the electron capture process be Q1. The nuclear reaction can be written as:
Let the amount of energy released during the positron capture process be Q2. The nuclear reaction can be written as:
me = Mass of an electron
c = Speed of light
Q-value of the electron capture reaction is given as:
It can be inferred that if Q2 > 0, then Q1 > 0; Also, if Q1> 0, it does not necessarily mean that Q2 > 0.
In other words, this means that if β+ emission is energetically allowed, then the electron capture process is necessarily allowed, but not vice-versa. This is because the Q-value must be positive for an energetically allowed nuclear reaction.
Q .23 In a periodic table the average atomic mass of magnesium is given as 24.312 u. The average value is based on their relative natural abundance on earth. The three isotopes and their masses are 2412Mg (23.98504u), 2512Mg(24.98584u) and 2612Mg (25.98259u). The natural abundance of 2412Mg is 78.99% by mass. Calculate the abundances of the other two isotopes.
Answer: Let the abundance of 2512Mg be x%
The abundance of 2612Mg = (100 – 78.99 -x)%
= (21.01 – x)%
The average atomic mass of magnetic
24.312 = 23.98504 × 78.99 + 24.98584x + 25.98259(21.01−x)) /100
24.312 x 100= 1894.57 + 24.98584x + 545. 894 – 25.98259x
2431.2 = 2440.46 – 0.99675x
0.99675x = 2440.46 – 2431.2
0.99675x = 9.26
x = 9.26/0.99675
x = 9.290%
Abundance of 2512Mg is 9.290%
The abundance of 2612Mg = (21.01 – x)%
= (21.01 -9.290 )% = 11.71%
Q . 24 The neutron separation energy is defined as the energy required toremove a neutron from the nucleus. Obtain the neutron separationenergies of the nuclei 4120Ca and 2713Al from the following data:m(4020Ca ) = 39.962591 um(4120Ca ) = 40.962278 um(2613Al ) = 25.986895 um(2713Al ) = 26.981541 u
Answer:
When the nucleons are separated from 20Ca41 → 20 Ca40 + 0n1
Mass defect, Δm = m (20 Ca40) + mn – m(20 Ca41)
= 39.962591 + 1.008665 – 40.962278
= 0.008978 amu
Neutron separation energy = 0.008978 x 931 MeV = 8.362 MeV
Similarly, 13Al27 → 13 Al26 + 0n1
Mass defect, Δm = m (13 Al26) + mn – m(13Al27)
= 25.986895 + 1.008665 – 26.981541
= 26.99556 – 26.981541 = 0.014019 amu
Neutron separation energy = 0.014019 x 931 MeV
= 13.051 MeV
Q . 25 A source contains two phosphorous radionuclides 3215P (T1/2 = 14.3d) and 3315P(T1/2 = 25.3d). Initially, 10% of the decays come from 3315 P. How long one must wait until 90% do so?
Answer:
Let initially there be N1 atoms of
32/15P
and N2 atoms of
32/15P
and let their decay constants be
λ1
and
λ2
respectively
Since initially the activity of
32/15P
is 1/9 times that of
32/15P
we have
(i) Let after time t the activity of
32/15P
be 9 times that of
32/15P
(ii) Dividing equation (ii) by (i) and taking the natural log of both sides we get
where
λ2 = 0.048/ day
and
λ1 = 0.027/ day
t comes out to be 208.5 days
Q . 26 Under certain circumstances, a nucleus can decay by emitting a particle more massive than an α-particle. Consider the following decay processes:
223/88 Ra →209/82 Pb + 14/6 C
223/88 Ra →219/86 Rn + 4/2 He
Calculate the Q-values for these decays and determine that both are energetically allowed.
Answer:
Take a
14/6 C
emission nuclear reaction:
223/88 Ra →209/82 Pb + 14/6 C
We know that:
Mass of
223/88 Ra
m1 = 223.01850 u
Mass of
209/82 Pb
m2 = 208.98107 u
Mass of
14/6 C
, m3 = 14.00324 u
Hence, the Q-value of the reaction is given as:
Q = (m1 − m2 − m3) c2
= (223.01850 − 208.98107 − 14.00324) c2
= (0.03419 c2) u
But 1 u = 931.5 MeV/c2
∴Q = 0.03419 × 931.5
= 31.848 MeV
Hence, the Q-value of the nuclear reaction is 31.848 MeV. Since the value is positive, the reaction is energetically allowed.
Now take a
4/2 He
emission nuclear reaction:
223/88→229/86 Rn + 4/2 He
We know that:
Mass of
223/88 Ra
m1 = 223.01850
Mass of
219/82 Rn
m2 = 219.00948
Mass of
4/2 He
, m3 = 4.00260
Q-value of this nuclear reaction is given as:
Q = (m1 − m2 − m3) c2
= (223.01850 − 219.00948 − 4.00260) C2
= (0.00642 c2) u
= 0.00642 × 931.5 = 5.98 MeV
Hence, the Q value of the second nuclear reaction is 5.98 MeV. Since the value is positive, the reaction is energetically allowed.
Q . 27 Consider the fission of 23892U by fast neutrons. In one fission event,no neutrons are emitted and the final end products, after the betadecay of the primary fragments, are 14058Ce and 9944Ru. Calculate Qfor this fission process. The relevant atomic and particle massesarem(23892U ) =238.05079 um(14058Ce ) =139.90543 um(9944Ru ) = 98.90594 u
Answer: Given: The mass of U 92 238 is 238.05079 u, the mass of C 58 140 e is 139.90543 u and the mass of R 44 99 u is 98.90594 u.
Since, in the fission of U 92 238 , 10 β − particles decay from parent nucleus.
The nuclear reaction is given as,
U 92 238 + n 0 1 → C 58 140 e+ R 44 99 u+10 e −1 0
The Q value of the reaction process are given as,
Q=( m ′ 1 + m 4 – m ′ 2 – m ′ 3 −10 m e ) c 2 (1)
Where, the atomic mass of nuclei of U 92 238 , C 58 140 e, R 44 99 u are m ′ 1 , m ′ 2 , m ′ 3 respectively and the mass of a neutron is m 4 .
The atomic masses of nuclei are given as,
[ m ′ 1 = m 1 −92 m e m ′ 2 = m 2 −58 m e m ′ 3 = m 3 −44 m e ](2)
By substituting the values of atomic masses of nuclei from the equation (2) to equation (1), we get
Q=( m 1 −92 m e + m 4 − m 2 −58 m e − m 3 +44 m e −10 m e ) c 2
Where, the atomic mass of U 92 238 , C 58 140 e, R 44 99 u are m 1 , m 2 , m 3 respectively and the mass of electron is m e .
Since, 1 u=931.5 MeV/ c 2
By substituting the given values in the above expression, we get
Q=( m 1 + m 4 – m 2 – m 3 ) c 2 =( 238.0507+1.008665−139.90543−98.90594 ) c 2 =( 0.247995 c 2 ) u =231.1 MeV
Hence, the Qvalue of fission process is 231.1 MeV.
Q . 28 Consider the D–T reaction (deuterium–tritium fusion)
(a) Calculate the energy released in MeV in this reaction from the
data:
m(21H )=2.014102 u
m(31H ) =3.016049 u
(b) Consider the radius of both deuterium and tritium to be approximately 2.0 fm. What is the kinetic energy needed to overcome the coulomb repulsion between the two nuclei? To what temperature must the gas be heated to initiate the reaction? (Hint: Kinetic energy required for one fusion event =average thermal kinetic energy available with the interacting particles = 2(3kT/2); k = Boltzman’s constant, T = absolute temperature.)
Answer:
The Q value is given as
Q = Δm x 931 MeV
= (m (1H2) + m(1H3) – m(2He4) – mn) x 931
=( 2.014102 + 3.016049- 4.002603-1.00867) x 931
Q = 0.0188 x 931 = 17.58 MeV
(b) Repulsive potential energy of two nuclei when they touch each other is
= e2/4πϵ0(2r)
Where ε0 = Permittivity of free space
4Πϵ0 = 9 x 109 Nm2C-2
= (23.04 x 10-29)/(4 x 10-15)
= 5. 76 x 10-14 J
Kinetic energy needed to overcome the coulomb repulsion between the two nuclei is
K.E = 5. 76 x 10-14 J
K.E= 2 x (3/2) KT
K is the Boltzmann constant = 1.38 x 10-23
T = K.E/3K = 5. 76 x 10-14/(3 x 1.38 x 10-23)
= 5. 76 x 10-14/(4.14 x 10-23)
= 1.3913 x 109 K
Q . 29 Obtain the maximum kinetic energy of β-particles, and the radiation frequencies of γ decays in the decay scheme shown in Fig. 13.6. You are given that
m (198Au) = 197.968233 u
m (198Hg) =197.966760 u
Answer: It can be observed from the given γ-decay diagram that γ1 decays from the 1.088 MeV energy level to the 0 MeV energy level.
Hence, the energy corresponding to γ1-decay is given as:
E1 = 1.088 − 0 = 1.088 MeV
hν1= 1.088 × 1.6 × 10−19 × 106 J
Where,
h = Planck’s constant = 6.6 × 10−34 Js
ν1 = Frequency of radiation radiated by γ1-decay
It can be observed from the given γ-decay diagram that γ2 decays from the 0.412 MeV energy level to the 0 MeV energy level.
Hence, the energy corresponding to γ2-decay is given as:
E2 = 0.412 − 0 = 0.412 MeV
hν2= 0.412 × 1.6 × 10−19 × 106 J
Where,
ν2 = Frequency of radiation radiated by γ2-decay
It can be observed from the given γ-decay diagram that γ3 decays from the 1.088 MeV energy level to the 0.412 MeV energy level.
Hence, the energy corresponding to γ3-decay is given as:
E3 = 1.088 − 0.412 = 0.676 MeV
hν3= 0.676 × 10−19 × 106 J
Where,
ν3 = Frequency of radiation radiated by γ3-decay
Mass of
m(198/78 Au)
= 197.968233 u
Mass of
m(198/80 Hg)
= 197.966760 u
1 u = 931.5 MeV/c2
Energy of the highest level is given as:
β1 decays from the 1.3720995 MeV level to the 1.088 MeV level
∴Maximum kinetic energy of the β1 particle = 1.3720995 − 1.088
= 0.2840995 MeV
β2 decays from the 1.3720995 MeV level to the 0.412 MeV level
∴Maximum kinetic energy of the β2 particle = 1.3720995 − 0.412
= 0.9600995 MeV
Q 30. Calculate and compare the energy released by a) fusion of 1.0 kg of hydrogen deep within the sun and b) the fission of 1.0 kg of 235U in a fission reactor.
Answer: Amount of hydrogen, m = 1 kg = 1000 g
(a) 1 mole, i.e., 1 g of hydrogen contains 6.023 x 1023 atoms. Therefore, 1000 g of hydrogen contains 6.023 x 1023 x 1000 atoms.
In Sun, four hydrogen nuclei fuse to form a helium nucleus and will release energy of 26 MeV
Energy released by the fusion of 1 kg of hydrogen,
E1 = (6.023 x 1023 x 1000 x 26)/4
E1= 39.16 x 1026 MeV
(b) Amount of 235U = 1 kg = 1000 g
1 mole, i.e., 235 g of uranium contains 6.023 x 1023 atoms. Therefore, 1000 g of uranium contains (6.023 x 1023 x 1000)/235 atoms.
The energy released during the fission of one atom of 235U = 200 MeV
Energy released by the fission of 1 Kg of 235U,
E2= (6.023 x 1023 x 1000 x 200)/235
E2 = 5.1 x 1026 MeV
(E1/E2) = (39.16 x 1026/5.1 x 1026)
= 7.67
The energy released in the fusion of hydrogen is 7.65 times more than the energy released during the fission of Uranium.
Q 13.31. Suppose India had a target of producing by 2020 AD, 200,000 MW of electric power, ten per cent of which was to be obtained from nuclear power plants. Suppose we are given that, on average, the efficiency of utilization (i.e. conversion to electric energy) of thermal energy produced in a reactor was 25%. How much amount of fissionable uranium would our country need per year by 2020? Take the heat energy per fission of 235U to be about 200MeV.
Answer:
Electric power to be generated = 2 x 105 MW = 2 x 105 x 106 J/s = 2 x 1011 J/s
10 % of the amount is obtained from the nuclear power plant
P1 = (10/100) x 2 x 1011 x 60 x 60 x 24 x 365 J/year
Heat energy released during per fission of a 235U nucleus, E = 200 MeV
Efficiency of the reactor = 25%
The amount of energy converted to electrical energy in fission is (25/100) x 200 = 50 MeV
= 50 x 1.6 x 10-19 x 106 = 80 x 10-13 J
Required number of atoms for fission per year
= [(10/100) x 2 x 1011 x 60 x 60 x 24 x 365]/80 x 10-13
= 788400 x 1023 atoms
1 mole, i.e., 235 g of 235U contains 6.023 x 1023 atoms
Mass of 6.023 x 1023 atoms of 235U = 235 x 10-3 kg
Mass of 788400 x 1023 atoms of 235U
=[ (235 x 10-3)/(6.023 x 1023) ] x 78840 x 1024
= 3. 076 x 104 Kg
The mass of uranium needed per year is 3.076 x 104 Kg